In organic chemistry, enolates are organic anions derived from the deprotonation of carbonyl (RR'C=O) compounds. Rarely isolated, they are widely used as reagents in the synthesis of …

Aug 16, 2022 · Enolates can be formed through removing the proton on carbons adjacent to a carbonyl (i.e. the “ alpha-carbon “). The resulting anions are much more stable than typical …

Since the negative charge of an enolate anion is delocalized over the alpha-carbon and the oxygen, as shown earlier, electrophiles may bond to either atom. Reactants having two or …

Apr 16, 2025 · Enolates are reactive intermediates in organic chemistry that play a central role in forming carbon–carbon bonds. They are formed by deprotonating the α-hydrogen of carbonyl …

The conjugate base resulting from the loss of an α-proton in an aldehyde, ketone, ester or amide is an enolate. If we rewrite the above equilibrium using hydroxide ions we obtain the following. …

Enolates, or oxyallyl anions, are versatile reagents for the formation of α-substituted carbonyl compounds and are therefore important intermediates for the synthesis of complex molecules.

Enolates are resonance-stabilized anions that play a crucial role in organic chemistry as versatile nucleophiles. Understanding their formation, reactions, and applications is essential for …

In the enolate, neither structure has charge separation and both structures are relatively close together in energy. One structure has the stronger C=O bond, but the other has negative …

Trying to put it as simply as possible, enols are compounds that have alcohol groups, -OH, substituted directly onto alkenes, C=C, hence "alkene-ols" or enols. Enols can be viewed a …

An enolate is a resonance-stabilized anion formed during the base-catalyzed tautomerization of carbonyl compounds. The process begins when a base removes an alpha proton (a hydrogen …